Anodize

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Information on Anodize Films:

At Hohman Plating, we offer:

  • Chromic Acid Anodize
  • Sulfuric Acid Anodize
  • Hard Anodize

Aluminum anodization is a significant commercial process. Anodic films on aluminum are electrically insulating (dielectric) and tend to minimize galvanic corrosion where aluminum is in contact with other metals. The anodic film formed by anodizing also provides an excellent paint base and helps insure adhesion of organic coatings such as zinc chromate primer, paints, and lubricants. Aluminum anodization is typically considered in terms of the anodizing processes classified in AMS and Mil-A-8625.

Benefits of Anodize on Aluminum:

  • Corrosion prevention
  • Various Colors
  • Electrical insulation “dielectric”
  • Wear resistance
  • Wear plus lubrication (PTFE impregnated hard anodize only)

Chromic Anodize

Specifications:

  • AMS Standard
  • ASTM Standard
  • Mil-A-8625 TI

Color: There are no color variances for Chromic Anodize.

Thickness: .05 to .2 mils

Chromic acid anodize coatings are preferred when there is a high possibility of solution entrapment in joints, recesses, and weldments because the chromic acid leaves no corrosive residue. The chromic acid is inhibitive to aluminum and, thus, is especially good for coating aluminum castings. The characteristics of the film vary somewhat with the type of electrolyte used.

Chromic acid-produced films are more dense, very thin, and darker in color. The overall thickness of the coating formed is 50 percent penetration in the substrate and 50 percent growth over the original dimension of the part. Chromic acid films are typically harder than sulfuric acid films of the same thickness.

Sulfuric Anodize

Specifications:

  • AMS Standard
  • ASTM Standard
  • Mil-A-8625 TII

Color: Black, Red, Blue, Green, and Gold are available dyes for Sulfuric Anodize.

Thickness: 0.1 to 1.0 mil

The sulfuric acid process is the most common method for anodization. The sulfuric acid process produces films of greater thickness and is particularly suited for applications where hardness and resistance to abrasion is required. However, where parts are subjected to considerable stress, such as aircraft parts, the possible presence of the corrosive acid residue is undesirable. Because the coating is a conversion coating, only 67 percent of the coating thickness is measurable by dimensional growth. The other 33 percent of the coating thickness does not effect the dimensions as this is the amount of aluminum used to form the coating.

The porous nature of sulfuric acid films prior to sealing is used to particular advantage in the production of colored surface finishes on aluminum and its alloys. The porous anodize coating absorbs dyes well, and subsequent sealing helps to prevent color loss in service. Although dyed anodized films are reasonably color-fast, they have a tendency to bleach under prolonged direct sunlight. This can be improved by some of the new non-organic dyes not affected by time and light.

Hard Anodize

Specifications:

  • AMS Standard
  • ASTM Standard
  • Mil-A-8625 TIII

Color: There are no color variances available for Hard Anodize.

Thickness: 1 to 2 mils

The hard anodizing process also uses a sulfuric acid electrolyte, but the bath is maintained at higher sulfuric acid concentration, lower temperature, and higher current density, which increase film crystallinity. The overall thickness of the coating formed is 50 percent penetration in the substrate and 50 percent growth over the original dimension of the part.  Parts processed by this method have a hardness around 65 Rockwell “C”. Hard anodic coatings generally have increased surface roughness as well as having the property of being softer on the top surface than down in the core of the coating. Such coatings may be processed oversized and then lapped down to final dimensions. Lapping of a hard anodized surface results in an exceedingly smooth, hard finish resembling polished stone. Hard anodizing is an excellent electrical insulator, and base for paint, dry film lubricants and other coatings.

Sealing of hard coating is not recommended unless corrosion resistance is a factor. Wear resistance is reduced by sealing. Hard coatings may also reduce fatigue strength. These factors should be considered in proposed use of parts subjected to cyclic loads. Generally, hard coatings should not be used on parts, which during rework would normally require restoring of dimensional tolerances because of wear of hard coated surfaces.When the hard anodize is impregnated with PTFE, the coating not only has great wear and abrasion resistance, but also has improved lubricating properties. Some applications for the impregnated coating are; valves, sliding parts, hinges, cams, pistons, and gears.



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